A nonenolizable imino-N-heterocyclic carbene ligand and corresponding silver (I) metal complex

Karl S. Coleman; Sarim Dastgir; Guy Barnett; Maria J.P. Alvite; Andrew R. Cowley; Malcolm L.H. Green

doi:10.1016/j.jorganchem.2005.07.020

A nonenolizable imino-N-heterocyclic carbene ligand and corresponding silver (I) metal complex

Karl S. Coleman^*, Sarim Dastgir, Guy Barnett, Maria J.P. Alvite, Andrew R. Cowley, Malcolm L.H. Green

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The nonenolizable imino-N-heterocyclic carbene ligand precursor [1-t-butylimidazolium-3-{C(Ph)N(Ph)}] chloride has been synthesised. The corresponding silver (I) complex Ag(C∧imine)Cl; where C∧imine = [1-t-butylimidazolium-2-ylidene-3-{C(Ph)N(Ph)}], was prepared by reaction with Ag₂O. All of the compounds have been structurally characterized by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	5591-5596
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	24-25
DOIs	https://doi.org/10.1016/j.jorganchem.2005.07.020
Publication status	Published - 1 Dec 2005
Externally published	Yes

Keywords

Bidentate ligands
Carbene
Carbene-imine ligands
N-heterocyclic carbene
Silver

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10.1016/j.jorganchem.2005.07.020

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title = "A nonenolizable imino-N-heterocyclic carbene ligand and corresponding silver (I) metal complex",

abstract = "The nonenolizable imino-N-heterocyclic carbene ligand precursor [1-t-butylimidazolium-3-{C(Ph)N(Ph)}] chloride has been synthesised. The corresponding silver (I) complex Ag(C∧imine)Cl; where C∧imine = [1-t-butylimidazolium-2-ylidene-3-{C(Ph)N(Ph)}], was prepared by reaction with Ag2O. All of the compounds have been structurally characterized by single crystal X-ray diffraction.",

keywords = "Bidentate ligands, Carbene, Carbene-imine ligands, N-heterocyclic carbene, Silver",

author = "Coleman, {Karl S.} and Sarim Dastgir and Guy Barnett and Alvite, {Maria J.P.} and Cowley, {Andrew R.} and Green, {Malcolm L.H.}",

year = "2005",

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doi = "10.1016/j.jorganchem.2005.07.020",

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volume = "690",

pages = "5591--5596",

journal = "Journal of Organometallic Chemistry",

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T1 - A nonenolizable imino-N-heterocyclic carbene ligand and corresponding silver (I) metal complex

AU - Coleman, Karl S.

AU - Dastgir, Sarim

AU - Barnett, Guy

AU - Alvite, Maria J.P.

AU - Cowley, Andrew R.

AU - Green, Malcolm L.H.

PY - 2005/12/1

Y1 - 2005/12/1

N2 - The nonenolizable imino-N-heterocyclic carbene ligand precursor [1-t-butylimidazolium-3-{C(Ph)N(Ph)}] chloride has been synthesised. The corresponding silver (I) complex Ag(C∧imine)Cl; where C∧imine = [1-t-butylimidazolium-2-ylidene-3-{C(Ph)N(Ph)}], was prepared by reaction with Ag2O. All of the compounds have been structurally characterized by single crystal X-ray diffraction.

AB - The nonenolizable imino-N-heterocyclic carbene ligand precursor [1-t-butylimidazolium-3-{C(Ph)N(Ph)}] chloride has been synthesised. The corresponding silver (I) complex Ag(C∧imine)Cl; where C∧imine = [1-t-butylimidazolium-2-ylidene-3-{C(Ph)N(Ph)}], was prepared by reaction with Ag2O. All of the compounds have been structurally characterized by single crystal X-ray diffraction.

KW - Bidentate ligands

KW - Carbene

KW - Carbene-imine ligands

KW - N-heterocyclic carbene

KW - Silver

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U2 - 10.1016/j.jorganchem.2005.07.020

DO - 10.1016/j.jorganchem.2005.07.020

M3 - Article

AN - SCOPUS:27744463372

SN - 0022-328X

VL - 690

SP - 5591

EP - 5596

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 24-25

ER -

A nonenolizable imino-N-heterocyclic carbene ligand and corresponding silver (I) metal complex

Abstract

Keywords

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