Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide

Muhammad Sharif; Ralf Jackstell; Sarim Dastgir; Badria Al-Shihi; Matthias Beller

doi:10.1002/cctc.201600760

Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide

Muhammad Sharif, Ralf Jackstell, Sarim Dastgir, Badria Al-Shihi^*, Matthias Beller

^*Corresponding author for this work

QEERI - Energy Center

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).

Original language	English
Pages (from-to)	542-546
Number of pages	5
Journal	ChemCatChem
Volume	9
Issue number	4
DOIs	https://doi.org/10.1002/cctc.201600760
Publication status	Published - 21 Feb 2017

Keywords

1,3-butadiene
carbon dioxide
lactone
palladium
telomerization

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abstract = "A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).",

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AU - Jackstell, Ralf

AU - Dastgir, Sarim

AU - Al-Shihi, Badria

AU - Beller, Matthias

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KW - 1,3-butadiene

KW - carbon dioxide

KW - lactone

KW - palladium

KW - telomerization

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ER -

Efficient and selective Palladium-catalyzed Telomerization of 1,3-Butadiene with Carbon Dioxide

Abstract

Keywords

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