TY - JOUR
T1 - Erratum
T2 - Temperature-, Light-, and Soft X-ray-Induced Spin Crossover in a Single Layer of FeII-Pyrazolylborate Molecules in Direct Contact with Gold (Journal of Physical Chemistry (2018) 122:1 (727-731) DOI: 10.1021/acs.jpcc.7b11874)
AU - Bairagi, Kaushik
AU - Bellec, Amandine
AU - Fourmental, Cynthia
AU - Tong, Yongfeng
AU - Iasco, Olga
AU - Lagoute, Jérôme
AU - Chacon, Cyril
AU - Girard, Yann
AU - Rousset, Sylvie
AU - Choueikani, Fadi
AU - Otero, Edwige
AU - Ohresser, Philippe
AU - Sainctavit, Philippe
AU - Boillot, Marie Laure
AU - Mallah, Talal
AU - Repain, Vincent
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/12/20
Y1 - 2018/12/20
N2 - In the main text, the coverage was estimated as discussed in the Supporting Information (SI) to be less than a monolayer. Complementary experiments detailed below indicate that in fact the molecular coverage is 1.57 ± 0.25 ML. The calibration of the molecular coverage is a delicate task, and as discussed in the SI we tried by several means to evaluate it. We also compared the edge jump of our sample to a 130 nm sample as described in ref 1. Nonetheless, in the case of molecular thicknesses inferior to the escape length of the electrons, the background due to the substrate (here Au(111)) must be taken into account and the edge jump cannot be compared to a thick molecular film. We improved our calibration by first measuring our sample by scanning tunneling microscopy (STM) at 5 K and then transferring the sample in a ultrahigh vacuum (UHV) suitcase to the synchrotron beamline for X-ray absorption spectroscopy (XAS) measurements. Indeed, we prepared a sample of FeII((3,5-(CH3)2Pz)3BH)2 molecules sublimated (from a homemade Knudsen cell as described in the main text) on a Au(111) single crystal (prepared by standard sputtering and annealing procedure as described in the main text). A typical STM topography is presented in Figure 1a where molecular islands are observed with some molecules in second layer. The coverage is determined by measuring the area of the molecular islands taking into account the first and the second molecular layers with respect to the image area. We thus measured a coverage of 0.48 ± 0.06 ML (average on 8 areas at different positions on the sample). As the diffusing molecules, corresponding to the stripes in between the islands in the STM image, are ignored, the coverage might be slightly underestimated. The same sample has been transferred to the DEIMOS beamline within a few hours under UHV (base pressure: 7.10-9 mbar) and measured at the L2,3-edge of Fe. The spectra at room temperature (Figure 1b) present an edge-jump of 1.1 ± 0.1%. For the sample presented in the main text, the edge jump was 3.6%, which therefore corresponds to a coverage of 1.57 ± 0.25 ML which is in rather good agreement with the calibration of ref 3. Thus, for the results presented in the main text, the proportion of molecules in the second layer cannot be neglected. Especially, the proportion of molecules in high spin state given in the main text corresponds to a global measurement over the two molecular layers knowing that the spin state and the switching properties of the molecules are most probably different between the ones in the first layer in contact with gold and the ones in the second layer (Figure Presented).
AB - In the main text, the coverage was estimated as discussed in the Supporting Information (SI) to be less than a monolayer. Complementary experiments detailed below indicate that in fact the molecular coverage is 1.57 ± 0.25 ML. The calibration of the molecular coverage is a delicate task, and as discussed in the SI we tried by several means to evaluate it. We also compared the edge jump of our sample to a 130 nm sample as described in ref 1. Nonetheless, in the case of molecular thicknesses inferior to the escape length of the electrons, the background due to the substrate (here Au(111)) must be taken into account and the edge jump cannot be compared to a thick molecular film. We improved our calibration by first measuring our sample by scanning tunneling microscopy (STM) at 5 K and then transferring the sample in a ultrahigh vacuum (UHV) suitcase to the synchrotron beamline for X-ray absorption spectroscopy (XAS) measurements. Indeed, we prepared a sample of FeII((3,5-(CH3)2Pz)3BH)2 molecules sublimated (from a homemade Knudsen cell as described in the main text) on a Au(111) single crystal (prepared by standard sputtering and annealing procedure as described in the main text). A typical STM topography is presented in Figure 1a where molecular islands are observed with some molecules in second layer. The coverage is determined by measuring the area of the molecular islands taking into account the first and the second molecular layers with respect to the image area. We thus measured a coverage of 0.48 ± 0.06 ML (average on 8 areas at different positions on the sample). As the diffusing molecules, corresponding to the stripes in between the islands in the STM image, are ignored, the coverage might be slightly underestimated. The same sample has been transferred to the DEIMOS beamline within a few hours under UHV (base pressure: 7.10-9 mbar) and measured at the L2,3-edge of Fe. The spectra at room temperature (Figure 1b) present an edge-jump of 1.1 ± 0.1%. For the sample presented in the main text, the edge jump was 3.6%, which therefore corresponds to a coverage of 1.57 ± 0.25 ML which is in rather good agreement with the calibration of ref 3. Thus, for the results presented in the main text, the proportion of molecules in the second layer cannot be neglected. Especially, the proportion of molecules in high spin state given in the main text corresponds to a global measurement over the two molecular layers knowing that the spin state and the switching properties of the molecules are most probably different between the ones in the first layer in contact with gold and the ones in the second layer (Figure Presented).
UR - http://www.scopus.com/inward/record.url?scp=85059022685&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.8b11550
DO - 10.1021/acs.jpcc.8b11550
M3 - Comment/debate
AN - SCOPUS:85059022685
SN - 1932-7447
VL - 122
SP - 29080
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
IS - 50
ER -