Investigation of the Inorganic Compounds NaMV2(PO4)3 (M = Fe, Co, Ni) as Anode Materials for Sodium-Ion Batteries

Alaa Alkhateeb, Hamdi Ben Yahia

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The new compounds NaMV2(PO4)(3) (M = Fe, Co, Ni) were synthesized via a sol-gel synthesis route, and their crystal structures were refined using the Rietveld method from X-ray powder diffraction data. NaCoV2(PO4)(3) was also characterized by TGA, cyclic voltammetry, and galvanostatic cycling. The three phases crystallize with the orthorhombic symmetry and the space group Imma. The structures are isotypic to the stuffed alpha-CrPO4-type structure and contain two vacant sites in which two sodium atoms can be intercalated. When NaCoV2(PO4)(3) is cycled at a 1C rate in the voltage ranges of 0.1-3 and 0.7-3 V vs Na+/Na, it delivers specific capacities of 190 and 75 mA h/g, respectively, with an average operation potential of similar to 1.4 V. This attests to the electrochemical activity of this compound and indicates that the alpha-CrPO4 -type compounds could be suitable for hosting other guest ions.
Original languageEnglish
Pages (from-to)30799-30807
Number of pages9
JournalACS Omega
Volume5
Issue number48
DOIs
Publication statusPublished - 8 Dec 2020

Keywords

  • Excellent cycling stability
  • Bond-valence parameters
  • Nickel-oxide
  • Crystal-structure
  • Carbothermic reduction
  • Electrode materials
  • Electrochemical properties
  • Carbon
  • Intercalation
  • Performance

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