Methylene blue adsorption via maize silk powder: Kinetic, equilibrium, thermodynamic studies and residual error analysis

Seyed Mohammadreza Miraboutalebi, Soheil Kordmirza Nikouzad, Mohammad Peydayesh, Nima Allahgholi, Leila Vafajoo, Gordon McKay*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

137 Citations (Scopus)

Abstract

The potential of maize silk powder (MS) as a natural, widely available and low-cost agricultural waste in order to adsorb methylene blue (MB) from an aqueous solution has been studied. The adsorbent surface morphology has been studied using SEM and FTIR. The effect of operating conditions such as contact time, solution pH and initial MB concentration and the important frequently missed parameters such as salt effect (using NaCl and Na2HPO4), temperature effect (for ΔH°, ΔG° and ΔS°), solution pH and detailed error analysis have been determined. A rate study indicated the process followed pseudo-second order kinetics. The adsorption equilibrium was modeled for best fit using ten commonly-used isotherm models and the Jovanovic equation gave the best correlation of the experimental data.

Original languageEnglish
Pages (from-to)191-202
Number of pages12
JournalProcess Safety and Environmental Protection
Volume106
DOIs
Publication statusPublished - 2017

Keywords

  • Error analysis
  • Isotherm
  • Maize silk
  • Methylene blue adsorption
  • Nonlinear regression

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