TY - JOUR
T1 - One-pot synthesis of a CdS–MoS2 / CNTs nano-composite for photocatalytic hydrogen production under visible light
AU - Imam, Muhammad Danyal
AU - Badreldin, Ahmed
AU - Kakosimos, Konstantinos E.
AU - Al-Hashimi, Mohammed
AU - Abdel-Wahab, Ahmed
N1 - Publisher Copyright:
© 2023 Hydrogen Energy Publications LLC
PY - 2024/1/2
Y1 - 2024/1/2
N2 - The need to meet growing energy demands of global society in a sustainable fashion requires the development of techniques and processes to reduce dependence on fossil fuels and transit to renewable energy sources. Environmentally benign technologies for alternative fuel production in the form of hydrogen can be developed via heterogenous photocatalysis, a process based on utilization of solar energy. To this end, a cadmium sulfide (CdS) based photocatalyst was developed, doped with MoS2 in a one-pot solvothermal synthesis technique, and coupled with multi-walled carbon nanotubes (MWCNTs) as a carbonaceous support. The material exhibiting the highest rate of hydrogen evolution, CM5C3, involved a MWCNTs loading of 3% and MoS2 loading of 5%. Compared to pure CdS synthesized with the same adapted procedure, the 3% CNT loading improved the rate of hydrogen production by nearly 7-fold, and the optimal 5% MoS2 loading further improved the performance by 60%. CM5C3, achieved an apparent quantum efficiency of 7.34%, a 26 fold increase compared to pure CdS. FESEM and HRTEM imaging confirmed the nanorodlike growth of CdS-MoS2 on the CNT surface, with elemental mapping confirming homogenous dispersion of MoS2 and CNTs. In addition, lattice fringe spacings indicated the presence of cubic and hexagonal CdS growing predominantly along the (111) and (002) planes respectively, in addition to MoS2 distributed throughout the crystal lattice. XRD analysis confirmed the presence of hexagonal and cubic CdS, however, MoS2 phases were not registered perhaps due to the low concentration present in the bulk of the material. XPS survey scans showed the presence of C, Cd, Mo, and S only, with trace oxygen impurities. Peak deconvolution indicated the presence of characteristic peaks for CdS and MoS2, in addition to evidence of the presence of Cd-C bonds, indicating strong CdS heterojunctions to the CNT surface.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
AB - The need to meet growing energy demands of global society in a sustainable fashion requires the development of techniques and processes to reduce dependence on fossil fuels and transit to renewable energy sources. Environmentally benign technologies for alternative fuel production in the form of hydrogen can be developed via heterogenous photocatalysis, a process based on utilization of solar energy. To this end, a cadmium sulfide (CdS) based photocatalyst was developed, doped with MoS2 in a one-pot solvothermal synthesis technique, and coupled with multi-walled carbon nanotubes (MWCNTs) as a carbonaceous support. The material exhibiting the highest rate of hydrogen evolution, CM5C3, involved a MWCNTs loading of 3% and MoS2 loading of 5%. Compared to pure CdS synthesized with the same adapted procedure, the 3% CNT loading improved the rate of hydrogen production by nearly 7-fold, and the optimal 5% MoS2 loading further improved the performance by 60%. CM5C3, achieved an apparent quantum efficiency of 7.34%, a 26 fold increase compared to pure CdS. FESEM and HRTEM imaging confirmed the nanorodlike growth of CdS-MoS2 on the CNT surface, with elemental mapping confirming homogenous dispersion of MoS2 and CNTs. In addition, lattice fringe spacings indicated the presence of cubic and hexagonal CdS growing predominantly along the (111) and (002) planes respectively, in addition to MoS2 distributed throughout the crystal lattice. XRD analysis confirmed the presence of hexagonal and cubic CdS, however, MoS2 phases were not registered perhaps due to the low concentration present in the bulk of the material. XPS survey scans showed the presence of C, Cd, Mo, and S only, with trace oxygen impurities. Peak deconvolution indicated the presence of characteristic peaks for CdS and MoS2, in addition to evidence of the presence of Cd-C bonds, indicating strong CdS heterojunctions to the CNT surface.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
KW - Carbon heterojunction
KW - CdS photocatalyst
KW - MoS2
KW - Photocatalytic hydrogen evolution
KW - Reaction
KW - Visible light hydrogen evolution
UR - http://www.scopus.com/inward/record.url?scp=85174047633&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2023.09.173
DO - 10.1016/j.ijhydene.2023.09.173
M3 - Article
AN - SCOPUS:85174047633
SN - 0360-3199
VL - 51
SP - 1267
EP - 1278
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
ER -