Ruthenium-alkylidene initiated cyclopolymerization and tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization: Facile access to cycloolefin-based polymers

Santhosh Kumar Podiyanachari; Hassan S. Bazzi; Mohammed Al-Hashimi

doi:10.2174/1385272825666210921091807

Ruthenium-alkylidene initiated cyclopolymerization and tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization: Facile access to cycloolefin-based polymers

Santhosh Kumar Podiyanachari, Hassan S. Bazzi^*, Mohammed Al-Hashimi^*

^*Corresponding author for this work

Research output: Contribution to journal › Short survey › peer-review

1 Citation (Scopus)

Abstract

Synthesis of cycloolefin-based polymers via metathesis-accompanied cyclopoly-merization and tandem Ring-Opening/Ring-Closing Metathesis (RO/RCM) polymerization are undergoing exciting developments and emerging as an area of great interest in the field of polymer synthesis. Among the conventional polymerization techniques, both cyclopolymerization and tandem polymerization give access to highly functional cycloolefin ring-based polymers. This review provides an overview of the synthesis of such cycloolefin-based conjugated and non-conjugated polymers following cyclopolymerization and tandem RO/RCM polymerization methodologies.

Original language	English
Pages (from-to)	2791-2805
Number of pages	15
Journal	Current Organic Chemistry
Volume	25
Issue number	22
DOIs	https://doi.org/10.2174/1385272825666210921091807
Publication status	Published - Nov 2021
Externally published	Yes

Keywords

Cyclopolymerization
Poly(acetylene)s
Poly(olefin)s
Ring-closing metathesis
Ring-opening metathesis
Ruthenium-alkylidene
Tandem polymerization

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10.2174/1385272825666210921091807

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@article{1d4d63ab984147f58328948bc687b46c,

title = "Ruthenium-alkylidene initiated cyclopolymerization and tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization: Facile access to cycloolefin-based polymers",

abstract = "Synthesis of cycloolefin-based polymers via metathesis-accompanied cyclopoly-merization and tandem Ring-Opening/Ring-Closing Metathesis (RO/RCM) polymerization are undergoing exciting developments and emerging as an area of great interest in the field of polymer synthesis. Among the conventional polymerization techniques, both cyclopolymerization and tandem polymerization give access to highly functional cycloolefin ring-based polymers. This review provides an overview of the synthesis of such cycloolefin-based conjugated and non-conjugated polymers following cyclopolymerization and tandem RO/RCM polymerization methodologies.",

keywords = "Cyclopolymerization, Poly(acetylene)s, Poly(olefin)s, Ring-closing metathesis, Ring-opening metathesis, Ruthenium-alkylidene, Tandem polymerization",

author = "Podiyanachari, {Santhosh Kumar} and Bazzi, {Hassan S.} and Mohammed Al-Hashimi",

note = "Publisher Copyright: {\textcopyright} 2021 Bentham Science Publishers.",

year = "2021",

month = nov,

doi = "10.2174/1385272825666210921091807",

language = "English",

volume = "25",

pages = "2791--2805",

journal = "Current Organic Chemistry",

issn = "1385-2728",

publisher = "Bentham Science Publishers",

number = "22",

}

Ruthenium-alkylidene initiated cyclopolymerization and tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization: Facile access to cycloolefin-based polymers. / Podiyanachari, Santhosh Kumar; Bazzi, Hassan S.; Al-Hashimi, Mohammed.
In: Current Organic Chemistry, Vol. 25, No. 22, 11.2021, p. 2791-2805.

Research output: Contribution to journal › Short survey › peer-review

TY - JOUR

T1 - Ruthenium-alkylidene initiated cyclopolymerization and tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization

T2 - Facile access to cycloolefin-based polymers

AU - Podiyanachari, Santhosh Kumar

AU - Bazzi, Hassan S.

AU - Al-Hashimi, Mohammed

PY - 2021/11

Y1 - 2021/11

N2 - Synthesis of cycloolefin-based polymers via metathesis-accompanied cyclopoly-merization and tandem Ring-Opening/Ring-Closing Metathesis (RO/RCM) polymerization are undergoing exciting developments and emerging as an area of great interest in the field of polymer synthesis. Among the conventional polymerization techniques, both cyclopolymerization and tandem polymerization give access to highly functional cycloolefin ring-based polymers. This review provides an overview of the synthesis of such cycloolefin-based conjugated and non-conjugated polymers following cyclopolymerization and tandem RO/RCM polymerization methodologies.

AB - Synthesis of cycloolefin-based polymers via metathesis-accompanied cyclopoly-merization and tandem Ring-Opening/Ring-Closing Metathesis (RO/RCM) polymerization are undergoing exciting developments and emerging as an area of great interest in the field of polymer synthesis. Among the conventional polymerization techniques, both cyclopolymerization and tandem polymerization give access to highly functional cycloolefin ring-based polymers. This review provides an overview of the synthesis of such cycloolefin-based conjugated and non-conjugated polymers following cyclopolymerization and tandem RO/RCM polymerization methodologies.

KW - Cyclopolymerization

KW - Poly(acetylene)s

KW - Poly(olefin)s

KW - Ring-closing metathesis

KW - Ring-opening metathesis

KW - Ruthenium-alkylidene

KW - Tandem polymerization

UR - http://www.scopus.com/inward/record.url?scp=85121301067&partnerID=8YFLogxK

U2 - 10.2174/1385272825666210921091807

DO - 10.2174/1385272825666210921091807

M3 - Short survey

AN - SCOPUS:85121301067

SN - 1385-2728

VL - 25

SP - 2791

EP - 2805

JO - Current Organic Chemistry

JF - Current Organic Chemistry

IS - 22

ER -

Ruthenium-alkylidene initiated cyclopolymerization and tandem ring-opening/ring-closing metathesis (RO/RCM) polymerization: Facile access to cycloolefin-based polymers

Abstract

Keywords

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