Synthesis and electrochemical investigation of oligomeric and polymeric ferrocenyl-amides having cyclohexyl, phenylene, and lysyl spacers

Khaled A. Mahmoud; Heinz Bernhard Kraatz

doi:10.1007/s10904-007-9179-3

Synthesis and electrochemical investigation of oligomeric and polymeric ferrocenyl-amides having cyclohexyl, phenylene, and lysyl spacers

Khaled A. Mahmoud, Heinz Bernhard Kraatz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

This paper discusses the synthesis and characterization of a series of ferrocene oligo- and polyamides having phenylene, cyclohexyl, or lysyl spacer groups separating the electroactive ferrocene groups. The oligomeric materials are characterized by spectroscopic means and display an electrochemical signature indicating very limited electronic communication between the ferrocenes. The ferrocene-phenylene polymer however, shows clear indications of weak electronic interactions.

Original language	English
Pages (from-to)	69-80
Number of pages	12
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	18
Issue number	1
DOIs	https://doi.org/10.1007/s10904-007-9179-3
Publication status	Published - Mar 2008
Externally published	Yes

Keywords

Electrochemistry
Ferrocene
Ferrocenediamine
Polymer

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10.1007/s10904-007-9179-3

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AU - Kraatz, Heinz Bernhard

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N2 - This paper discusses the synthesis and characterization of a series of ferrocene oligo- and polyamides having phenylene, cyclohexyl, or lysyl spacer groups separating the electroactive ferrocene groups. The oligomeric materials are characterized by spectroscopic means and display an electrochemical signature indicating very limited electronic communication between the ferrocenes. The ferrocene-phenylene polymer however, shows clear indications of weak electronic interactions.

AB - This paper discusses the synthesis and characterization of a series of ferrocene oligo- and polyamides having phenylene, cyclohexyl, or lysyl spacer groups separating the electroactive ferrocene groups. The oligomeric materials are characterized by spectroscopic means and display an electrochemical signature indicating very limited electronic communication between the ferrocenes. The ferrocene-phenylene polymer however, shows clear indications of weak electronic interactions.

KW - Electrochemistry

KW - Ferrocene

KW - Ferrocenediamine

KW - Polymer

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DO - 10.1007/s10904-007-9179-3

M3 - Article

AN - SCOPUS:38549093066

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SP - 69

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JO - Journal of Inorganic and Organometallic Polymers and Materials

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IS - 1

ER -

Synthesis and electrochemical investigation of oligomeric and polymeric ferrocenyl-amides having cyclohexyl, phenylene, and lysyl spacers

Abstract

Keywords

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