Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

Jameel Al Thagfi; Sarim Dastgir; Alan J. Lough; Gino G. Lavoie

doi:10.1021/om100321n

Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

Jameel Al Thagfi, Sarim Dastgir, Alan J. Lough, Gino G. Lavoie

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

Original language	English
Pages (from-to)	3133-3138
Number of pages	6
Journal	Organometallics
Volume	29
Issue number	14
DOIs	https://doi.org/10.1021/om100321n
Publication status	Published - 26 Jul 2010
Externally published	Yes

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abstract = "A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.",

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AU - Al Thagfi, Jameel

AU - Dastgir, Sarim

AU - Lough, Alan J.

AU - Lavoie, Gino G.

PY - 2010/7/26

Y1 - 2010/7/26

N2 - A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

AB - A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

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U2 - 10.1021/om100321n

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M3 - Article

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JO - Organometallics

JF - Organometallics

IS - 14

ER -

Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

Abstract

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